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Selected Rheological Properties of RS3/4 Type Resistant Starch
 
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Publication date: 2017-12-31
 
Pol. J. Food Nutr. Sci. 2017;67(4):293–299
 
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ABSTRACT
This study was aimed at determining the effect of acetylation degree and crosslinking of retrograded starch with adipic acid on selected rheological properties of prepared pastes and gels. The esterification of retrograded starch allowed obtaining preparations with various degrees of substitution with residues of acetic (0.7-11.2 g/100 g) and adipic acids (0.1-0.3 g/100 g). Acetylation and crosslinking caused a decrease in amylose content of the preparations (3-21 g/100 g). Solubility of the preparations in water, in a wide range of variability, was increasing along with an increasing degree of acetylation and with a decreasing degree of crosslinking (19-100 g/100 g). Values of most of the rheological coefficients determined based on the flow curves of the prepared pastes and mechanical spectra of gels (3.5∙sn, 4.2<τ0C<70 Pa, 0.26<tgα<0.57) were increasing in a wide range along with increasing crosslinking of starch. Changes in the rheological properties upon the effect of double modification were not the sum of changes proceeding as a result of single modifications. Instead, interaction of both factors was observed. The conducted modifications enable modelling the properties of produced preparations.
 
REFERENCES (33)
1.
Akintayo C.O., Akintayo E.T., Preparation, composition and physico-chemical characteristics of native, oxidized and acetylated African yambean (Sphenostylis Sternocarpa) starches. Adv. in Nat. Appl. Sci., 2009, 3, 196–203.
 
2.
Ali T.M., Hasnain A., Functional and morphological characterization of low-substituted acetylated white sorghum (Sorghum bicolor) starch. Int. J. Polym. Anal. Ch., 2011, 16, 187–198.
 
3.
Berski W., Ptaszek A., Ptaszek P., Ziobro R., Kowalski G., Grzesik M., Achremowicz B., Pasting and rheological properties of oat starch and its derivatives. Carbohydr. Polym., 2011, 83, 665–671.
 
4.
Bushra M., Xu X.X., Pan S.Y., Microwave assisted acetylation of mung bean starch and the catalytic activity of potassium carbonate in free solvent reaction. Starch/Stärke, 2013, 65, 236–243.
 
5.
Diop C.I.K., Li H.L., Xie B.J., Shi J., Combinatorial effects of mechanical activation and chemical stimulation on the microwave assisted acetylation of corn (Zea mays) starch. Starch/Stärke, 2011, 63, 96–105.
 
6.
Emeje M., Kalita R., Isimi C., Buragohain A., Kunle O., Ofoefule S., Synthesis, physicochemical characterization, and functional properties of an esterified starch from an underutilized source in Nigeria. Afr. J. Food Agric. Nutr. Dev., 2012, 12, 7001–7018.
 
7.
Global Industry Analysts, INC. 2015. Starch: A Global Strategic Business Report – Highlights.
 
8.
Han F., Liu M., Gong H., Lü S., Ni B., Zhang B., Synthesis, characterization and functional properties of low substituted acetylated corn starch. Int. J. Biol. Macromol., 2012, 50, 1026–1034.
 
9.
Haralampu S. G., Resistant starch – a review of the physical properties and biological impact of RS3. Carbohydr. Polym., 2000, 41, 3, 285–292.
 
10.
Huang J., Schols H.A., Jin Z., Sulmann E., Voragen A.G.J., Characterization of differently sized granule fractions of yellow pea, cowpea and chickpea starches after modification with acetic anhydride and vinyl acetate. Carbohydr. Polym., 2007, 67, 11–20.
 
11.
Jane J., Xu A., Radosavljevic M., Seib P.A., Location of amylose in normal starch granules. I. Susceptibility of amylose and amylopectin to cross-linking reagents. Cereal Chem., 1992, 69, 4, 405–409.
 
12.
Kapelko M., Zięba T., Golachowski A., Gryszkin A., Effect of the production method on the properties of RS3/RS4 type resistant starch. Part 1. Properties of retrograded starch (RS3) produced under various conditions and its susceptibility to acetylation. Food Chem., 2012, 135, 1494–1504.
 
13.
Kapelko M., Zięba T., Michalski A., Effect of the production method on the properties of RS3/RS4 type resistant starch. Part 2. Effect of a degree of substitution on the selected properties of acetylated retrograded starch. Food Chem., 2012a, 135, 2035–2042.
 
14.
Kapelko M., Zięba T., Michalski A., Gryszkin A., Effect of cross-linking degree on selected properties of retrograded starch adipate. Food Chem., 2015, 167, 124–130.
 
15.
Kapelko-Żeberska M., Zięba T., Spychaj R., Gryszkin A., Acetylated adipate of retrograded starch as RS ¾ type resistant starch. Food Chem., 2015, 188, 365-369.
 
16.
Leszczyński W., Resistant starch – classification, structure, production. Pol. J. Food Nutr. Sci., 2004, 13/54, 37–50.
 
17.
Morrison W.R., Laignelet B., An improved colorimetric procedure for determining apparent and total amylose in cereal and other starches. J. Cereal Sci., 1983, 1, 9–20.
 
18.
Muljana H., Picchioni F., Heeres H.J, Janssen L.P.B.M., Green starch conversions: Studies on starch acetylation in densified CO2. Carbohydr. Polym., 2010, 82, 653–662.
 
19.
Richter M., Augustat S., Schierbaum F., Ausgewählte Methoden der Stärkechemie. 1968, VEB Fachbuch Verlag Leipzig.
 
20.
Sajilata M.G., Singhal R.S., Kulkarni P.R., Resistant starch – A review. Compreh. Rev. Food Sci. Food Safety, 2006, 5, 1–17.
 
21.
Schramm G., Aspects of rheometry. 1994, in: A Practical Approach to Rheology and Rheometry. 2nd Edition (ed. G. Schramm). Gebrueder HAAKE GmbH, pp. 15–35.
 
22.
Simsek S., Ovando-Martínez M., Whitney K., Bello-Pérez L., Effect of acetylation, oxidation and annealing on physicochemical properties of bean starch. Food Chem., 2012, 134, 1796–1803.
 
23.
Singh A.V., Nath N.K., Synthesis, characterization, and compatibility study of acetylated starch with lamivudine. J. Therm. Anal. Calorim., 2012, 108, 307–313.
 
24.
Singh H., Sodhi N.S., Singh N., Structure and functional properties of acetylated sorghum starch. Int. J. Food Prop., 2012, 15, 312–325.
 
25.
Song J.Y., Park J.H., Shin M., The effects of annealing and acid hydrolysis on resistant starch level and the properties of cross-linked RS4 rice starch. Starch/Stärke, 2011, 63, 147–153.
 
26.
Wang S., Copeland L., New insights into loss of swelling power and pasting profiles of acid hydrolyzed starch granules. Starch/Stärke, 2012, 64, 538–544.
 
27.
Wani I.A., Sogi D.S., Gill B.S., Physicochemical properties of acetylated starches from some Indian kidney bean (Phaseolus vulgaris L.) cultivars. Int. J. Food Sci. Technol., 2012, 47, 1993–1999.
 
28.
Wurzburg O.B., Modified Starches - Properties and Uses. 1987, Boca Raton Florida CRS Press Inc.
 
29.
Yu S.X., Mu T.H., Zhang M., Ma M.M., Zhao Z.K., Effects of retrogradation and further acetylation on the digestibility and physicochemical properties of purple sweet potato flour and starch. Starch/Stärke, 2015, 67, 892 – 902.
 
30.
Zaragoza E.F., Zapata E.S., Sendra E., Sayas E., Navarro C., Fernández-López J., Pérez-Alvarez J.A., Resistant starch as prebiotic: A review. Starch/Stärke, 2011, 63, 406–415.
 
31.
Zięba T., Juszczak L., Gryszkin A., Properties of retrograded and acetylated starch preparations. Part 2. Dynamics of saccharification with amyloglucosidase and rheological properties of resulting pastes and gels. LWT – Food Sci. Technol., 2011, 44, 1321–1327.
 
32.
Zięba T., Kapelko M., Szumny A., Effect of preparation method on the properties of potato starch acetates with an equal degree of substitution. Carbohydr. Polym, 2013, 94, 193–198.
 
33.
Zięba T., Gryszkin A., Kapelko M., Selected properties of acetylated adipate of retrograded starch. Carbohydr. Polym., 2014, 99, 687–691.
 
 
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