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Physicochemical and Sensory Properties with Special Emphasis on Thermal Characteristics of Whey Butter from Gouda Cheese Production Compared to Milk Butter
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Department of Dairy Science and Quality Management, Faculty of Food Sciences, University of Warmia and Mazury in Olsztyn, Oczapowskiego 7, 10–719 Olsztyn, Poland
Oskar Michał Brożek   

Department of Dairy Science and Quality Management, University of Warmia and Mazury in Olsztyn, Oczapowskiego 7, 10-719, Olsztyn, Poland
Submission date: 2022-07-20
Acceptance date: 2022-10-18
Online publication date: 2022-11-14
Publication date: 2022-11-14
Pol. J. Food Nutr. Sci. 2022;72(4):407–419
The aim of this study was to characterise milk fat from whey butter and to identify potential differences between whey butter (WB) and sweet cream butter (milk butter – MB). The fatty acid (FA) profile, thermal properties, colour parameters, texture properties, and sensory attributes of MB and WB were compared. The values of texture properties (firmness, brittleness, and cohesiveness) and colour parameters (values of b* and the yellowness index) of WB were lower than MB. The sensory analysis showed lower values of consistency descriptors (firmness, brittleness, cohesiveness), a less intense nutty and milky aroma, and a more intense cheesy aroma and taste in WB than in MB. WB was more abundant in monounsaturated, polyunsaturated, and long-chain FAs, including C18:0, C18:1 Σt, C18:1 Σc, C18:2, C18:3, and C18:2 c9, t11, and it was less abundant in saturated and medium-chain FAs, including C10:0, C12:0, C14:0, C14:1, C15:0, C16:0, and C16:1, relative to MB. Water content (MB vs WB and the corresponding fats) and thermal history (single vs repeated heating and cooling treatments) affected differential scanning calorimetry curves and phase transition peaks. The principal component analysis revealed that the FA profile influenced the crystallisation and melting peaks of MB fat (MBF) and WB fat (WBF). WBF crystallisation occurred at a lower temperature, was characterised by lower enthalpy, and proceeded more rapidly than MBF crystallisation. Various fat fractions had different melting characteristics, and most WBF fractions were characterised by lower melting enthalpy and a smaller maximum difference in heat flow than MBF. Whey butter and milk butter differed in physicochemical properties and sensory attributes, and their thermal profiles depended on the FA profile, water content, and thermal history.
This research did not receive any specific grant from funding agencies in the public, commercial, or not-for-profit sectors.
This research did not receive any specific grant from funding agencies in the public, commercial, or not-for-profit sectors.
Amal, A.H. (2009). Fatty acid composition, textural and organoleptic properties of whey butter. Journal of Food and Dairy Sciences, 34(4), 3081–3094.
Amara-Dali, W.B, Lesieur, P., Artzner, F., Karray, N., Attia, H., Ollivon, M. (2007). Anhydrous goat's milk fat: thermal and structural behaviors studied by coupled differential scanning calorimetry and X-ray diffraction. 2. Influence of cooling rate. Journal of Agricultural and Food Chemistry, 55(12), 4741–4751.
Anankanbil, S., Larsen, M.K., Weisbjerg, M.R., Wiking, L. (2018). Effects of variation in fatty acids and triglyceride composition on melting behavior in milk fat. Milk Science International, 71(2), 4–9.
Brighenti, M., Govindasamy-Lucey, S., Jaeggi, J.J., Johnson, M.E., Lucey, J.A. (2021). Effect of substituting whey cream for sweet cream on the textural and rheological properties of cream cheese. Journal of Dairy Science, 104(10), 10500–10512.
Brożek, O.M., Kiełczewska, K., Bohdziewicz, K. (2022a). Fatty acid profile and thermal characteristics of ovine and bovine milk and their mixtures. International Dairy Journal, 129, art. no. 105339.
Brożek, O.M., Kiełczewska, K., Bohdziewicz, K. (2022b). Characterisation of selected emulsion phase parameters in milk, cream and buttermilk. Polish Journal of Food and Nutrition Sciences, 72(1), 5–15.
Buldo, P., Larsen, M.K., Wiking, L. (2013). Multivariate data analysis for finding the relevant fatty acids contributing to the melting fractions of cream. Journal of the Science of Food and Agriculture, 93(7), 1620–1625.
Çetinkaya, A. (2021). A research on determination of some properties of butter made from creams extracted from whey and milk. European Journal of Agriculture and Food Sciences, 3(4), 19–24.
Couvreur, S., Hurtaud, C., Lopez, C., Delaby, L., Peyraud, J.L. (2006). The linear relationship between the proportion of fresh grass in the cow diet, milk fatty acid composition, and butter properties. Journal of Dairy Science, 89(6), 1956–1969.
Dobrzańska, A., Cais-Sokolińska, D. (2014). Measuring the brightness and coordinate trichromaticity milk protein preparations. Aparatura Badawcza i Dydaktycza, 19(3), 267–272 (in Polish, English abstract).
Fauquant, C., Briard, V., Leconte, N., Michalski, M.-C. (2005). Differently sized native milk fat globules separated by microfiltration: fatty acid composition of the milk fat globule membrane and triglyceride core. European Journal of Lipid Science and Technology, 107(2), 80–86.
Food and Agriculture Organization/World Health Organization. (2018). Codex Alimentarius: Standard for butter, CXS 279-1971. Amended in 2018. Food and Agriculture Organisation of the United Nations, Rome, Italy.
Fredrick, E., Van de Walle, D., Walstra, P., Zijtveld, J.H., Fischer, S., Van der Meeren, P., Dewettinck, K. (2011). Isothermal crystallization behaviour of milk fat in bulk and emulsified state. International Dairy Journal, 21(9), 685–695.
Gómez-Mascaraque, L.G., Kilcawley, K., Hennessy, D., Tobin, J.T., O'Callaghan, T.F. (2020). Raman spectroscopy: A rapid method to assess the effects of pasture feeding on the nutritional quality of butter. Journal of Dairy Science, 103(10), 8721–8731.
Hokkanen, S.P., Partanen, R., Jukkola, A., Frey, A.D., Rojas, O.J. (2021). Partitioning of the milk fat globule membrane between buttermilk and butter serum is determined by the thermal behaviour of the fat globules. International Dairy Journal, 112, art. no. 104863.
Hondoh, H., Ueno, S. (2016). Polymorphism of edible fat crystals. Progress in Crystal Growth and Characterization of Materials, 62(2), 398–399.
International Organization for Standardization. (2002). Milk fat – Preparation of fatty acid methyl esters (ISO Standard No. 15884).
International Organization for Standardization. (2010). Milk – Determination of fat content – Gravimetric method (Reference method) (ISO Standard No. 1211).
International Organization for Standardization. (2014). Sensory analysis. General guidelines for the selection, training and monitoring of selected assessors and expert sensory assessors (ISO Standard No. 8586).
International Organization for Standardization. (2016). Sensory analysis – Methodology – General guidance for establishing a sensory profile (ISO Standard No. 13299).
Jhanwar, A., Ward, R.E. (2014). Particle size distribution and lipid composition of skim milk lipid material. International Dairy Journal, 36(2), 110–117.
Jinjarak, S., Olabi, A., Jiménez-Flores, R., Walker, J.H. (2006). Sensory, functional, and analytical comparisons of whey butter with other butters. Journal of Dairy Science, 89(7), 2428–2440.
Jukkola, A., Rojas, O.J. (2017). Milk fat globules and associated membranes: Colloidal properties and processing effects. Advances in Colloid and Interface Science, 245, 92–101.
Kasapcopur, E., Mohammed, A.M., Colakoglu, A.S. (2021). Effects of differences in whey composition on the physicochemical properties of whey butter. International Journal of Dairy Technology, 74(3), 535–546.
Larsen, M.K., Andersen, K.K., Kaufmann, N., Wiking, L. (2014). Seasonal variation in the composition and melting behavior of milk fat. Journal of Dairy Science, 97(8), 4703–4712.
Lopez, C., Lesieur, P., Bourgaux, C., Ollivon, M. (2005). Thermal and structural behavior of anhydrous milk fat. 3. Influence of cooling rate. Journal of Dairy Science, 88(2), 511–526.
Lopez, C., Ollivon, M. (2009). Triglycerides obtained by dry fractionation of milk fat: 2. Thermal properties and polymorphic evolutions on heating. Chemistry and Physics of Lipids, 159(1), 1–12.
Macwan, S.R., Dabhi, B.K, Parmar, S.C., Aparnathi, K.D. (2016). Whey and its utilization. International Journal of Current Microbiology and Applied Sciences, 5(8), 134–155.
Mallia, S., Escher, F., Schlichtherle-Cerny, H. (2008). Aroma-active compounds of butter: a review. European Food Research and Technology, 226, 315–325.
Małkowska, M., Staniewski, B., Ziajka, J. (2021). Analyses of milk fat crystallization and milk fat fractions. International Journal of Food Properties, 24(1), 325–336.
Michalski, M.-C., Ollivon, M., Briard, V., Leconte, N., Lopez, C. (2004). Native fat globules of different sizes selected from raw milk: thermal and structural behavior. Chemistry and Physics of Lipids, 132(2), 247–261.
Nadeem, M., Mahud, A., Imran, M., Khalique, A. (2014). Enhancement of the oxidative stability of whey butter through almond (Prunus dulcis) peel extract. Journal of Food Processing and Preservation, 39(6), 591–598.
Nishanthi, M., Vasiljevic, T., Chandrapala, J. (2017). Properties of whey proteins obtained from different whey streams. International Dairy Journal, 66, 76–83.
Omar, K.A., Gounga, M.E., Liu, R., Mwinyi, W., Aboshora, W., Ramadhan, A.H., Sheha, K.A., Wang, X. (2017). Triacylglycerol composition, melting and crystallization profiles of lipase catalysed anhydrous milk fats hydrolysed. International Journal of Food Properties, 20(sup2), 1230–1245.
Panghal, A., Patidar, R., Jaglan, S., Chhikara, N., Khatkar, S.K., Gat, Y., Sindhu, N. (2018). Whey valorization: current options and future scenario – a critical review. Nutrition and Food Science, 48(3), 520–535.
Pathare, P.B., Opara, U.L., Al-Said, F.A.-J. (2013). Colour measurement and analysis in fresh and processed foods: A review. Food and Bioprocess Technology, 6(1), 36–60.
Sánchez, L., Pérez, M.D. (2012). Physical properties of dairy products. In I. Arana (Ed.), Physical Properties of Foods: Novel Measurement Techniques and Applications, CRC Press, Boca Raton, USA, pp. 355–398.
Smet, K., Coudijzer, K., Fredrick, E., De Campeneere, S., De Block, J., Wouters, J, Raes, K., Dewettinck, K. (2010). Crystallization behavior of milk fat obtained from linseed-fed cows. Journal of Dairy Science, 93(2), 495–505.
Staniewski, B., Smoczyński, M., Żulewska, J., Wiśniewska, K., Baranowska, M. (2020). Effect of model heat treatment conditions on selected properties of milk fat. International Journal of Dairy Technology, 73(3), 532–541.
Staniewski, B., Ogrodowska, D., Staniewska, K., Kowalik, J. (2021). The effect of triacylglycerol and fatty acid composition on the rheological properties of butter. International Dairy Journal, 114, art. no. 104913.
Tarapata, J., Łobacz, A., Żulewska, J. (2021). Physicochemical properties of skim milk gels obtained by combined bacterial fermentation and renneting: Effect of incubation temperature at constant inoculum level. International Dairy Journal, 123, art. no. 105167.
Tomaszewska-Gras, J. (2012). Detection of butter adulteration with water using differential scanning calorimetry. Journal of Thermal Analysis and Calorimetry, 108, 433–438.
Tomaszewska-Gras, J. (2013). Melting and crystallization DSC profiles of milk fat depending on selected factors. Journal of Thermal Analysis and Calorimetry, 113, 199–208.
Truong, T., Bansal, N., Sharma, R., Palmer, M., Bhandari, B. (2014). Effects of emulsion droplet sizes on the crystallisation of milk fat. Food Chemistry, 145, 725–735.
Viriato, R.L.S, de Souza Queirós, M., Neves, M.I.L., Ribeiro, A.P.B, Gigante, M.L. (2019). Improvement in the functionality of spreads based on milk fat by the addition of low melting triacylglycerols. Food Research International, 120, 432–440.